By PETER URBEN, Leslie Bretherick
Experiences of prior versions: 'an notable text...thoroughly prompt' Loss Prevention Bulletin 'a publication that are supposed to be in each laboratory, chemical plant, emergency reaction and hearth keep an eye on middle, tuition and faculty ... I commend this booklet to somebody taken with chemical security and hygiene' Chemical and Engineering information '..a publication that each chemist must have on their shelf' New Scientist 'This booklet remains to be an important resource of reference for all these approximately to embark upon unknown brews and concoctions of possible blameless chemical compounds' Chemistry and Industry'The indexes are very good, and there are very beneficial cross-references among various species and varied reactions.' selection 'It is additionally a truly necessary and fast access into the literature at the many volatile chemical substances which were synthesized and characterised in the course of the twentieth century.' selection 'Bretherick' is greatly permitted because the reference paintings on reactive chemical risks and is key for all these operating with chemical substances. It contains each chemical for which documented info on reactive dangers has been stumbled on. The textual content covers over 5000 components and compounds and as many back of secondary entries related to or extra compounds. considered one of its most precious gains is the large go referencing all through either sections which hyperlinks comparable compounds or incidents no longer evidently similar. The 6th variation has been thoroughly up to date and revised via Peter Urben and comprises documented info on risks and applicable references as much as 1999 quantity 1 is dedicated to precise details at the balance of the indexed compounds, or the reactivity of combinations of 2 or extra of them lower than numerous conditions. each one compound is pointed out through an UPAC-based identify, the CAS registry quantity, its empirical formulation and constitution. each one description of an incident or violent response supplies connection with the unique literature. each one chemical is assessed at the foundation of similarities in constitution or reactivity, and those teams are indexed alphabetically in quantity 2. the crowd entries comprise a whole directory of all of the compounds in quantity 1 assigned to that workforce to aid go referral to comparable compounds. quantity 2 additionally includes possibility subject entries prepared alphabetically, a few with lists. Appendices comprise a fireplace similar information desk for better chance chemical substances, indexes of registry numbers and chemical names in addition to reference abbreviations and a word list.
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Extra resources for Bretherick's Handbook of Reactive Chemical Hazards, Sixth Edition
Silver tetrafluorobromate [35967-89-6] AgBrF4 AgBrF4 See entry METAL POLYHALOHALOGENATES See other SILVER COMPOUNDS 0007. Silver bromate [7783-89-3] AgBrO3 AgOBrO2 Other reactants Yoshida, 1980, 133 MRH values for 16 combinations with oxidisable materials are given. 0/12 1. , Bull. Soc. Chim. , 1945, 12, 94–95 2. Pascal, 1960, Vol. 1, 1004 The bromate is a powerful oxidant, and unstable mixtures with sulfur ignite at 73–75° C, and with disulfur dibromide on contact . Hydrogen sulfide ignites on contact with the bromate .
Japan Kokai, 1975, 75 13 233 5. Steffens, H. D. , Chem. , 1979, 90, 209354 6. Scherbakov, V. K. , Chem. , 1979, 91, 76322 7. Barton, J. A. , Chem. , 1986, 22, 647–650 8. May, D. C. , J. Haz. , 1987, 17(1), 61–88 9. See entry DUST EXPLOSION INCIDENTS (reference 22) Finely divided aluminium powder or dust forms highly explosive dispersions in air , and all aspects of prevention of aluminium dust explosions are covered in 2 recent US National Fire Codes . The effects on ignition properties of impurities introduced by recycled metal used to prepare dust were studied .
M. , Chem. 86 kJ/g). While pure silver azide explodes at 340° C , the presence of impurities may cause explosion at 270° C. It is also impact-sensitive and explosions are usually violent . Its use as a detonator has been proposed. Application of an electric field to crystals of the azide will detonate them, at down to 100° C , and it may be initiated by irradiation with electron pulses of nanosecond duration . See other CATALYTIC IMPURITY INCIDENTS, IRRADIATION DECOMPOSITION INCIDENTS Ammonia Mellor, 1940, Vol.